Group (periodic table)

In chemistry, a group (also known as a family) is a vertical column in the periodic table of the chemical elements. There are 18 groups in the standard periodic table, including the d-block elements, but excluding the f-block elements.

The modern explanation of the pattern of the table is that the elements in a group have similar configurations of the outermost electron shells of their atoms (i.e. the same core charge), as most chemical properties are dominated by the orbital location of the outermost electron. There are three conventional ways of numbering: One using Arabic numerals, and two using Roman numerals. The Roman numeral names are the original traditional names of the groups; the Arabic numeral names are those recommended by the International Union of Pure and Applied Chemistry (IUPAC) to replace the old names in an attempt to reduce the confusion generated by the two older, but mutually confusing, schemes.

There is considerable confusion surrounding the two old systems in use (old IUPAC and CAS) that combined the use of Roman numerals with letters. Both systems agree on the Roman numerals, which indicate (approximately) the highest oxidation number of the elements in that group (and therefore indicates similar chemistry with other elements with the same Roman numeral), which proceeds in a linearly increasing fashion for the most part, once on the left of the table, and once on the right (see List of oxidation states of the elements), with some irregularities in the transition metals. However, the two systems use the letters differently.

In the old IUPAC system the letters A and B were designated to the left (A) and right (B) part of the table, while in the CAS system the letters A and B were designated to main group elements (A) and transition elements (B). The old IUPAC system was frequently used in Europe while the CAS was most common in America. The new IUPAC scheme was developed to replace both systems as they confusingly used the same names to mean different things. The new system simply numbers the groups increasingly from left to right on the standard periodic table. The IUPAC proposal was first circulated in 1985 for public comments,^[1] and was later included as part of the 1990 edition of the Nomenclature of Inorganic Chemistry.^[2]

Groups

The periodic table groups are as follows:

References

Footnotes

1. ^ Fluck, E. New notations in the periodic table. Pure & App. Chem. 1988, 60, 431-436.[1]
2. ^ Leigh, G. J. Nomenclature of Inorganic Chemistry: Recommendations 1990. Blackwell Science, 1990. ISBN 0632024941.

Background

• Scerri, E. R. The Periodic Table, Its Story and Its Significance, Oxford University Press, 2007. ISBN 978-0-19-530573-9.